Browsing by Subject "Lanthanum compounds"
Now showing items 1-10 of 10
-
Article
Catalytic behavior of La-Sr-Ce-Fe-O mixed oxidic/perovskitic systems for the NO+CO and NO+CH4+O2 (lean-NOx) reactions
(2000)Mixed oxides of the general formula La0.5SrxCeyFeOz were prepared by using the nitrate method and characterized by XRD and Mossbauer techniques. The crystal phases detected were perovskites LaFeO3 and SrFeO3-x and oxides ...
-
Article
Comparative study of the magnetic and magnetotransport properties of a metallic and a semiconducting member of the solid solution LaNixCo1-xO3
(2003)A metallic and a semiconducting member of the solid solution LaNixCo1-xO3 (x=0.2, 0.6) with their magnetic and magnetotransport properties was investigated. The members of the perovskite solid solution were found on opposite ...
-
Article
Growth of polycrystalline LaNi 1-xCo xO 3 (x = 0.3, 0.5) thin films on Si(100) by pulsed laser deposition
(2004)Polycrystalline LaNi 1_xCo xO 3 (x = 0.5, 0.3) thin films have been deposited on polished Si(lOO) substrates by pulsed laser deposition. The films are grown at 650°C in ambient oxygen pressure of 0.4 mbar with an incident ...
-
Article
La0.95Sr0.05Coo3: An efficient room-temperature thermoelectric oxide
(2004)Electric resistivity, thermal conductivity, and the thermopower of polycrystalline Sr-doped LaCoO3 with composition La 0.9Sr0.5CoO3 were measured. The crystal structure of the synthesized powders was determined by x-ray ...
-
Article
LaSrMnCoO6: A new cubic double perovskite oxide
(2003)Single-phase polycrystalline powder samples of the double perovskite oxide LaSrMnCoO6 were synthesized by the Pechini (citrate-gel) technique. The structural, magnetic and electrical properties of the obtained powders were ...
-
Article
A microporous Co2+ metal organic framework with single-crystal to single-crystal transformation properties and high CO2 uptake
(2015)The synthesis and characterization of {[Co9(INA)18(H2O)6]·11DMF·15H2O}∞ (Co9-INA·11DMF·15H2O) (INA- = the anion of isonicotinic acid) is reported. It exhibits a rigid 3D-porous structure with a Co9 repeating unit consisting ...
-
Article
Realization of La2MnVO6: Search for half-metallic antiferromagnetism?
(2002)Single-phase polycrystalline La2MnVO6 samples were synthesized by arc-melting and characterized by X-ray diffraction, magnetization and resistivity measurements. We find that the compound has cubic (space group Fm3̄m), ...
-
Article
Synergistic effects of crystal phases and mixed valences in La-Sr-Ce-Fe-O mixed oxidic/perovskitic solids on their catalytic activity for the NO+CO reaction
(2000)Mixed oxidic and perovskite-type materials based on the La, Sr, Ce and Fe elements were prepared using a mixture of nitrates salts and heating at 1000°C. Three groups of solids were synthesized: (i) La(1-y)Ce(y)FeO3 (y=0.2, ...
-
Article
Thermoelectric properties of LaNi1-xCoxO3 solid solution
(2003)The thermoelectric properties of the selected members of the LaNi 1-xCoxO3 solid solution were investigated. The electrical properties of the solution investigated were determined from the doping level. The substitution ...
-
Article
Understanding the synergistic catalytic effect between la2O 3 and CaO for the CH4 Lean De-NOx reaction: Kinetic and mechanistic studies
(2005)Doping of La2O3 crystallites with Ca2+ ions significantly enhances the intrinsic rate of NO reduction by CH4 in the presence of 5% O2 at 550°C compared to pure La 2O3 and CaO solids, while the opposite is true after doping ...